A chloride resistant high potential oxygen reducing biocathode based on a fungal laccase incorporated into an optimized Os-complex modified redox hydrogel

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A chloride resistant high potential oxygen reducing biocathode based on a fungal laccase incorporated into an optimized Os-complex modified redox hydrogel

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Publication Article, peer reviewed scientific
Title A chloride resistant high potential oxygen reducing biocathode based on a fungal laccase incorporated into an optimized Os-complex modified redox hydrogel
Author(s) Beyl, Yvonne ; Guschin, Dmitrii ; Shleev, Sergey ; Schuhmann, Wolfgang
Date 2011
English abstract
A chloride-resistant high-potential biocathode based on Trametes hirsuta laccase incorporated into an optimized Os-complex modified redox hydrogel (80 mV potential difference to the T1 Cu) is described. The bioelectrocatalytic activity towards O2 reduction is due to an intimate access of the polymer-bound Os-complex to the T1 Cu site. The chloride resistance of the biocathode is due to the tight binding of the polymer-bound Os-complex to the T1 Cu site.
DOI http://dx.doi.org/10.1016/j.elecom.2011.02.024 (link to publisher's fulltext)
Publisher Elsevier
Host/Issue Electrochemistry Communications;5
Volume 13
ISSN 1388-2481
Pages 474-476
Language eng (iso)
Subject(s) Oxygen reduction
Chloride resistance
Redox polymer
Os-complex
Biofuel cell cathode
Sciences
Research Subject Categories::NATURAL SCIENCES
Handle http://hdl.handle.net/2043/12855 Permalink to this page

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