Cover and uncover : chiral switching exploiting templating and layer-by-layer grafting

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Cover and uncover : chiral switching exploiting templating and layer-by-layer grafting

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Publication Article, peer reviewed scientific
Title Cover and uncover : chiral switching exploiting templating and layer-by-layer grafting
Author(s) Halhalli, Mahadeo ; Sellergren, Börje
Date 2013
English abstract
Consecutive grafting of crosslinked L-phenylalanine anilide, D-phenylalanine anilide and non-imprinted polymer layers on the surface of wide pore silica resulted in porous composite beads displaying enantiomeric discrimination reflecting the last grafted layer. This no longer holds for beads freed from silica, which instead display enantio-selectivity reflecting the first grafted layer.
DOI http://dx.doi.org/10.1039/c3cc41989d (link to publisher's fulltext)
Publisher Royal Society of Chemistry
Host/Issue Chemical Communications;64
Volume 49
ISSN 1359-7345
Pages 7111-7113
Language eng (iso)
Subject(s) Controlled/living radical polymerization
molecularly imprinted polymers
chain transfer polymerization
surface
nanoparticles
beads
Sciences
Research Subject Categories::NATURAL SCIENCES
Handle http://hdl.handle.net/2043/16599 (link to this page)

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